Borane dimethyl sulfide
Borane-methyl sulfide complex
CAS: 13292-87-0
Molecular Formula: C2H10BS
Borane dimethyl sulfide - Names and Identifiers
Borane dimethyl sulfide - Physico-chemical Properties
| Molecular Formula | C2H10BS |
| Molar Mass | 76.97 |
| Density | 1.287g/mLat 25°C |
| Melting Point | -40--37°C |
| Boling Point | ~34°C |
| Flash Point | 65°F |
| Water Solubility | reacts |
| Solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
| Appearance | Light yellow solution |
| Specific Gravity | 0.801 |
| Color | Colorless to pale yellow |
| BRN | 3663489 |
| Storage Condition | 2-8°C |
| Sensitive | Air & Moisture Sensitive |
| Refractive Index | 1.4570 |
| MDL | MFCD00013189 |
Borane dimethyl sulfide - Risk and Safety
| Risk Codes | R12 - Extremely Flammable R14/15 - R19 - May form explosive peroxides R20/22 - Harmful by inhalation and if swallowed. R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes R67 - Vapors may cause drowsiness and dizziness R65 - Harmful: May cause lung damage if swallowed R63 - Possible risk of harm to the unborn child R48/20 - R38 - Irritating to the skin R11 - Highly Flammable R22 - Harmful if swallowed R14 - Reacts violently with water R40 - Limited evidence of a carcinogenic effect R36 - Irritating to the eyes R21 - Harmful in contact with skin R36/37/38 - Irritating to eyes, respiratory system and skin. R37 - Irritating to the respiratory system |
| Safety Description | S36/37 - Wear suitable protective clothing and gloves. S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S36/39 - S33 - Take precautionary measures against static discharges. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S23 - Do not breathe vapour. S16 - Keep away from sources of ignition. S36 - Wear suitable protective clothing. S24/25 - Avoid contact with skin and eyes. S7/8 - S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S39 - Wear eye / face protection. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| UN IDs | UN 3399 4.3/PG 1 |
| WGK Germany | 3 |
| RTECS | PV5080000 |
| FLUKA BRAND F CODES | 10-13-23 |
| TSCA | Yes |
| HS Code | 29309090 |
| Hazard Class | 4.3 |
| Packing Group | II |
Borane dimethyl sulfide - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| introduction | borane dimethyl sulfide complex is a complex of diborane. Diborane (B2H6) is a toxic, spontaneous gas that is very easy to hydrolyze and oxidize. It must be handled with extreme care and must be transported and stored at temperatures below -20°C. |
| use | used with pinene to produce montelukast sodium and entecavir. Together with L-pyrrolidone alcohol supported by dendrimer, it is used for asymmetric reduction of indenone and tetrahydronaphthone. CBS-catalyzed asymmetric reduction of ferrocenyl -1, 3-diketone into chiral 1, 3-diol. Highly asymmetric reduction of ketones catalyzed by C3-symmetric tripoxylamide. Reactants are used as reducing agents for specific selection. Reactants participate in: · Hydroboration reaction/oxidation of cage compounds. |
Last Update：2024-04-10 22:29:15
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View History
Borane dimethyl sulfide
5-Amino-4-bromobenzothiazole
Trifluoroanisole
METHYL M-METHOXYPHENYLACETATE
2-Aminomethylazetidine
(2-AMINO-BENZOTHIAZOL-6-YL)-MORPHOLIN-4-YL-METHANONE
3-Pyrrolidinol, 1-(phenylmethyl)-, 3-(4-methylbenzenesulfonate)
sodiumperborate(nabo3)
Einecs 241-741-1
5-Amino-4-bromobenzothiazole
Trifluoroanisole
METHYL M-METHOXYPHENYLACETATE
2-Aminomethylazetidine
(2-AMINO-BENZOTHIAZOL-6-YL)-MORPHOLIN-4-YL-METHANONE
3-Pyrrolidinol, 1-(phenylmethyl)-, 3-(4-methylbenzenesulfonate)
sodiumperborate(nabo3)
Einecs 241-741-1